>Color mixing isn't quite THAT simple, sadly. Pigments don't
>mix like light and pure colors should. You tend to get
>muddy or gray colors when you try to get, say orange from
>red and yellow.
>
>Tinting one color to bias it a bit toward another will work
>fine, adding white to make a pale color will work too.
>Black may go toward green, blue or brown as you add it to
>other colors. Experiment with small batches, and then let
>it dry to see the true result. BE AFRAID, BE VERY AFRAID!
>
>Definitely don't mix something you think ought to work and
>spray your new pride and joy!

Larry,
Well said. The problem with trying to mix new colors from a manufacturer's existing colors is that each one of the mixed colors is made up of toners which are pure pigments for each of the base mixing colors. The combination of the toners, done properly, can make up, say, a beautiful "jump out at you" red.
However, when you try to tint this great red to another color by using another already mixed color the combination of base pigments in the colors may give quite different results due to the interaction of base pigments. The result may well be, as you said, muddy, gray, or washed out colors. There are exceptions as we have all had some degree of success at mixing/tinting colors from existing manufacturer's colors but it isn't usually the rule.
Metallics are made by using translucent color toners which allow the metallic effect to show through the color. Successfully tinting metallics is difficult and tends to result in washed out colors.