Warren,
First some questions before the possible answer. Did the paint lift under the flexi-tape, or did the paint lift at the parting line between the tape/masked surface and the area you wished the color to stay on?
Reason I ask is this. During my use of Brodak dope on a recent project I found that the vinyl type tapes (red and blue kinds) when used for masking curves and the like tended to not provide for very good paint to tape separation properties. The dried dope tended to kinda' slide off the vinyl mask mediums, leaving a very ugly parting line at the masked edge. Normal masking tape used in the same area's of coverage did not exhibit this kind of tendency. The 3M brand masking tape of standard make-up pulled up as per normal, leaving a nice sharp edge between masked and unmasked areas.
I think that because the vinyl flexi tapes are of such smooth surface make-up, they offer less adhesion to the paint that is being sprayed over them. Because the paint does not adhere to the tape surface, it pulls off the tape during masking removal, and may start the beginnings of lifted paint at the surface of the model. If you continue to pull the mask up the lifting of paint at the model surface tends to follow along with this.
What I did to minimize this tendency was as follows. I liked the way the flexi tape takes a corner so I continue to use it for this purpose. But I also re-mask over this tape with standard 3M brand masking tape as close to the flexi-tape edge as I can get, to reduce the exposure of the flexi-tape to paint application. When it's time to unmask I very carefully pull the mask up at 90 degrees to the model surface at a min., and at more acute angles if possible. The hope is of getting a clean masked line between model surfaces. Should the dope pull off the vinyl flexi-mask tape and start to make a mess of things, I cut the pulled paint with a blade, and continue on with the un-masking as best I can. This can tend to leave an ugly demarcation line between your colors. To clean this edge up I've found that a single edge razor blade, laid flat against the surface, and slowly pulled along the raised paint edge will cut the pulled paint of the mask off the surface leaving a nice clean paint edge. Hope this helps some.
This is what happened to me. But I'm kinda thinking like you regarding the prepped surface. Brodak primer can be sanded to almost a shine if fine enough sand paper is used. Smoothing a little rougher then 400 may help reduce the pulled paint related to this. I'm going to try 320 as the final sand in the near future, ..give the dope a little more mechanical grip to the model/primer surface. Regards.
Tony